Chemical Effects of Electric Current — Question 12
Back to all questionsQuestion 12
The process that you saw in Activity 11.7 is used for the purification of copper. A thin plate of pure copper and a thick rod of impure copper are used as electrodes. Copper from the impure rod is sought to be transferred to the thin copper plate. Which electrode should be attached to the positive terminal of the battery and why?
The thick rod of impure copper should be attached to the positive terminal of the battery in the purification process of copper. This is because, during the passage of electric current through copper sulphate solution, it breaks down into copper and sulphate ions. The positively charged copper ions are attracted to the negative terminal of the battery, where they get deposited on the thin plate of pure copper. Simultaneously, the impure copper rod, linked to the positive terminal, contributes copper ions to compensate for the loss in the solution. This ensures the overall purification of copper during the process.
Chapter Overview: Chemical Effects of Electric Current
This chapter explores how electric current affects liquids: which liquids conduct (electrolytes with ions) and which do not, the chemical effects observed (metal deposition, gas bubbles, colour change), and the practical applications of electrolysis and electroplating.
Board Exam Weightage: 4-6 marks | Difficulty: Moderate
Key Formulas & Concepts
| Concept | Details |
|---|---|
| Electrolysis of Water | 2H2O → 2H2 + O2 (hydrogen at cathode, oxygen at anode) |
| Electroplating Setup | Cathode: object to plate; Anode: plating metal; Electrolyte: plating metal's salt solution |
| PANIC Rule | Positive Anode, Negative Is Cathode |
| Conduction in Liquids | Requires free ions (dissolved salts, acids, bases) |
Must-Know Concepts
- Liquids with ions (salt solution, acids, bases) conduct electricity; pure water does not
- Chemical effects of current in liquids: metal deposition, gas evolution, colour change
- In electrolysis of water, hydrogen collects at cathode (double volume) and oxygen at anode
- Electroplating deposits a thin layer of desired metal on another object
- Chromium plating for shine and corrosion resistance; tin plating for food safety; zinc coating (galvanising) for rust prevention
- LED tester is more sensitive than a bulb for testing liquid conductivity
Electroplating Applications
| Plating Metal | Used On | Reason |
|---|---|---|
| Chromium | Car parts, taps, cycle handles | Shiny appearance, corrosion resistance |
| Gold/Silver | Jewellery | Attractive look at lower cost |
| Tin | Food cans | Non-toxic, prevents iron rusting |
| Zinc | Iron pipes, bridges, fences | Prevents rusting (galvanising) |
| Nickel | Coins, utensils | Durability, corrosion resistance |
Common Mistakes to Avoid
- Thinking pure/distilled water conducts electricity (it does not, no ions)
- Confusing anode (positive) and cathode (negative)
- Thinking electroplating changes the entire material (only a thin surface layer)
- Forgetting that electrolyte must be a salt of the plating metal
Scoring Tips
- Use PANIC to remember: Positive Anode, Negative Is Cathode
- Draw the electroplating setup with clear labels
- Test 5 household liquids mentally: which conduct and why
- Remember the 3 chemical effects: deposition, gas bubbles, colour change
Frequently Asked Questions
Q: How many marks does this chapter carry in the exam?
A: Approximately 4-6 marks in the annual exam.
Q: What question types are commonly asked?
A: MCQs (1 mark), Very Short Answer (2 marks), Short Answer (3 marks), and Long Answer / Diagram (5 marks).
Q: Is this chapter important for competitive exams?
A: Yes, concepts from this chapter appear in NTSE, Olympiad, and other science competitions.