Question 1(2018)
Choose the correct answer from the options given : The electrolysis of acidified water is an example of :
- Reduction
- Oxidation
- Redox reaction
- Synthesis
Redox reaction
Reason — Reaction at cathode: Hydrogen ions, H+ being the only positively charged ions migrate to the cathode. Since, the cathode is a reservoir of electrons , H+ ions gain an electron and become a neutral hydrogen atom. Therefore reduction takes place at cathode.
H+ + e- ⟶ H
H + H ⟶ H2
Reaction at anode : SO42- and OH- ions both migrate to the anode. OH-being lower in electrochemical series is discharged preferentially.
OH- ions loses an electron to the anode and becomes neutral OH. The combination of OH forms water with the liberation of oxygen, given off at anode.
OH- ⟶ OH + e-
OH + OH ⟶ H2O + O
O + O ⟶ O2
Therefore, oxidation takes place at anode. Hence, electrolysis of acidified water is an example of redox reaction