| Electrolytic dissociation | Ionisation |
|---|---|
| Separation of ions which are already present in an ionic compound | Formation of positively or negatively charged ions from molecules which are not initially in the ionic state. |
| Electrovalent compounds show dissociation e.g., potassium chloride, lead bromide, etc. | Polar covalent compounds show ionisation e.g., HCl, NH4OH etc., |
| KCl ⟶ K+ + Cl- |