(a) When Sodium sulphite reacts with HCl, effervescence occurs and a pungent gas (SO2) is evolved that turns acidified potassium dichromate paper from orange to green.
Na2SO3 + 2HCl ⟶ 2NaCl + H2O + SO2 ↑
Whereas, Sodium sulphate (Na2SO4) gives no visible reaction with HCl and no gas is evolved.
(b) Ammonium Chloride (NH4Cl) reacts with Ca(OH)2 to release ammonia gas (NH3) which has pungent smell, turns red litmus blue.
2NH4Cl + Ca(OH)2 ⟶ CaCl2 + 2H2O + 2NH3↑
Whereas, sodium chloride shows no reaction with Calcium hydroxide.
(c) Lead Nitrate (Pb(NO3)2) reacts with HCl, forms a white precipitate of lead chloride (PbCl2) which is soluble in hot water.
Pb(NO3)2 + 2HCl ⟶ PbCl2 ↓ + 2HNO3
However, when Silver nitrate reacts with HCl, it forms a white precipitate of silver chloride (AgCl) which is insoluble in hot water
AgNO3 + HCl ⟶ AgCl ↓ + HNO3