(a) White precipitate of barium sulphate is formed.
Reason — When a solution of zinc sulphate is added to a solution of barium chloride, a double displacement reaction occurs. This reaction involves the exchange of ions between the two compounds and a white precipitate of barium sulphate is formed.
ZnSO4 (aq) + BaCl2 (aq) ⟶ BaSO4 (s) + ZnCl2 (aq).
(b) Blue precipitate dissolves to form an inky blue/deep blue solution.
Reason — The light blue precipitate of copper(II) hydroxide (Cu(OH)2) dissolves in excess of ammonium hydroxide due to the formation of a deep blue complex, tetraamminecopper(II) ([Cu(NH3)4]2+), making it soluble.

