ICSE Class 10 Chemistry Question 66 of 93

Organic Chemistry — Question 66

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66
Question

Question 6(2017)

Give a balanced chemical equation for each of the following –

(i) Preparation of ethane from sodium propionate.

(ii) Action of alcoholic KOH on bromoethane.

Answer

(i) ethane from sodium propionate : ethane is formed

C2H5COONasodium propionate+NaOHsodalimeCaOΔC2H6ethane+Na2CO3\underset{\text{sodium propionate}}{\text{C}_2\text{H}_5\text{COONa}} + \underset{\text{sodalime}}{\text{NaOH}} \underset{\Delta}{\xrightarrow{\text{CaO}}} \underset{\text{ethane}}{\text{C}_2\text{H}_6} + \text{Na}_2\text{CO}_3

(ii) ethyl alcohol is formed.

C2H5-Br Bromoethane [ethyl bromide]+KOH [aq.] alcoholic KOHboilC2H5OH ethyl alcohol+KBr\underset{\text{ Bromoethane [ethyl bromide]}}{\text{C}_2\text{H}_5\text{-Br}} + \underset{\text{ alcoholic KOH}}{\text{KOH [aq.]}} \xrightarrow{\text{boil}} \underset{ \text{ ethyl alcohol}} {\text{C}_2\text{H}_5\text{OH}} + \text{KBr}